Lead Acetate when reacts with `A gives black ppt PbCl2

Lead Acetate when reacts with `A gives black ppt PbCl2
| Lead Acetate when reacts with `A', gives black ppt

A. PbCl2

B. PbCO3

C. PbCrO4

D. PbS

Please scroll down to see the correct answer and solution guide.

Right Answer is: D

SOLUTION

Try to recall the properties of Lead acetate.
When H2S gas is passed through the solution of (CH3COO)2Pb, black ppt. of PbS is formed.
(CH3COO)2Pb+H2S2CH3COOH+PbS­
Black ppt.
But,
With potassium chromate K2CrO4:
(CH3COO)2Pb+K2CrO4PbCrO4­+2CH3COOK
Lead chromate
(yellow ppt.)
On addition of HCl in (CH3COO)2Pb solution, white ppt of PbCl­2­ is formed in cold conditions, which dissolves on heating. On cooling, PbCl­2 reaooears as a white crystalline solid.
(CH3COO)2Pb+2HClPbCl2+2CH3COOH
dilLead chloride
(white ppt).
and same with NaHCO3,
(CH3COO)2Pb+2NaHCO3PbCO3+2CH3COONa
                                                   (white ppt)